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+ Acid Sulfate Soils – Is your worksite in a coastal, low lying area?

Is your worksite in a coastal, low lying area?

What are Acid Sulfate Soils?

Acid Sulfate Soils formed at the end of the last ice age when the sea level rose. Soil that was rich in iron or organic material became waterlogged with the sea water and sulfide from the water reacted with the iron from the soil creating iron sulfides. As long as the soil remains in its waterlogged state the pH remains neutral.

When do problems arise?

Problems arise when waterlogged Iron Sulfide rich soils are exposed to the atmosphere. The Iron Sulfide oxidises in the presence of air to form Sulfuric Acid (H2SO4). This process typically occurs during construction work, especially the construction of canalled waterfront developments from low lying land, where soil is excavated to form canals, and the soil is then piled on top of the nearby land. As the soil dries out it oxidises on interaction with the air.

An apparently small quantity of soil can, on oxidation, generate a large quantity of sulfuric acid which runs into the water and kills aquatic life. The resultant pH can become very low.

What other problems are caused?

Acid from acid sulphate soil can quickly attack concrete, and if building in acid sulfate soils it may be necessary to use acid resistant concrete.

What does it look like?

Acid Sulfate Soils can be classified into Potential Acid Sulfate Soils and Actual Acid Sulfate Soils. Potential Acid Sulfate Soil is not necessarily acidic but has the potential to become acidic. These soils are in a waterlogged state where the water prevents the oxidation of the Iron Sulfide. Actual Acid Sulfate Soils are Potential Acid Sulfate Soils that have been exposed to the atmosphere via a dropping water table or other mechanical disturbance.

Potential Acid Sulfate Soil looks like wet dark grey mud. Actual Acid Sulfate Soil can be yellow in appearance. The yellow colouring is formed by a mineral called jarosite (Potassium Iron Sulfate Hydroxide). Its presence is indicative of sulfates in the soil oxidising.

Can I tell if the area is likely to have Acid Sulfate Soils?

Naturally low lying coastal areas, especially those with casuarinas and melaleucas, are those likely to have Acid Sulfate Soils. In addition, Getex has maps of the coastal regions with areas likely to have Acid Sulfate Soils at various depths shown in graded colours.

I want to develop land that may be affected by acid sulfate soils - what requirements might I have to follow?

If you propose to carry out works where it is likely that

  • You will disturb more than 1 ton of soil, during for example the excavation of soil for the creation of basement parking and/or building foundations, drain maintenance or construction and dredging operations.
  • The works are expected to be lower than the water table.
  • Works are expected to lower the water table, such as occurs in the construction or maintenance of drains and the use of pumps to lower the natural groundwater level within and/or around a development site. Note: if your property is in “Class 5” land then activities on your property (such as those indicated above) may have an impact on Class 1-4 lands that adjoin your property, i.e. alter the ground water level below 1 metre Australian Height Datum (AHD).

OR

  • If your site has been identified as likely to be affected by Acid Sulfate Soil on an Acid Sulfate Soil map

Then Council approval, as far as Acid Sulfate Soils are concerned, will likely to be required.

What can be done?

Getex can test for the presence of Acid Sulfate Soil. Holes are drilled or dug to a minimum of 1 metre below the maximum planned depth of excavation. Samples are taken and field tested by oxidation with concentrated peroxide. The samples which field test positive are sent to a lab for more testing.

If the results are positive the soil must be managed correctly if disturbance is required. The excavated soil must be limed before disposal. Getex can advise on the correct procedures and the correct quantities of lime and can provide Management Plans for handling the soil.

+ pH – What is pH?

What is pH?

pH is a measure of the acidity, or hydrogen ion concentration, of an aqueous (watery liquid). Every water solution contains H+ ions. pH is the negative common logarithm of the hydrogen ion concentration expressed in mol/L.

Most of us know that water is H2O. When we draw it more correctly as H-O-H we can see that water can dissociate into H+ and OH-. Neutral water has a pH of 7. If more acid (H+ ions) is added the pH drops. The lower the pH the more acid the solution, however, because it is a logarithmic scale, a pH of 5 is 10 times more acid than a pH of 6, and a pH of 4 is 100 times more acid than a pH of 6. A pH of say 1 is very acid indeed.

Conversely, as solutions become less acid, or more alkaline, the pH rises above 7. A solution of pH 12 is very alkaline.

Some typical pH values are:

 

 

Strongly Acid

 

Acid

 

Neutral

 

Alkaline

 

Strongly Alkaline

 

pH

 

      2

 

       3

 

         7

 

     10

 

        12

 

Example

 

Ant venom
Gastric juice

 

Coca cola
Lemon juice

 

Pure water

 

Detergent

 

Household cleaner

 

Most substances have a pH in the range 0 to 14, although pH values outside this range do occur

pH may be measured by use of a pH meter or by using special indicator papers such as litmus which change colour at known pH values. pH may also be measured by titration.

pH effects can be very marked in the environment. More than 70% of Australian soils have either a very high or low pH. Australian soils are acidic because they are geologically old and have been leached of most of their minerals except sands and metal oxides, and in many cases they are residual sand deserts from earlier periods of aridity. Naturally acidic soils occupy about one third of Australia, but many agricultural soils in the Intensive Land-use Zone become more acidic as the result of removal of calcium in harvested product, leaching of nitrate and calcium from nitrogen-producing pastures, and use of acidifying fertilisers. The process is particularly rapid in high-rainfall pasture-based systems. Acid sulfate soils, generally found in low lying coastal areas, are not acid until they dry out and oxidise, releasing much sulfuric acid.

When rock surfaces are exposed to air and rain, a reaction can occur with the elements in the rock resulting in a change in the characteristics of the water that drains off. If the rock contains sulphides, a natural oxidation process can acidify the water. This is known as acid drainage (also acid rock drainage or acid mine drainage). As the water becomes more acidic, its capacity to leach out other elements from the rock, such as metals, increases. The resulting drainage can become very acidic and contain a number of harmful constituents. Although this is a natural process, mining activities can trigger this phenomenon by exposing large surface areas of rock to water and oxygen. The most significant newly exposed rock surfaces are in the fragmented pieces of waste rock that are removed from the ground and placed in dumps.

Contact GETEX for assistance with pH.

GETEX operates 24/7. Your call will be handled by experienced people with authority who can help you. We do not use message services.

+ Soil Contamination – How Clean is that…Fill, Site, Waste, Runoff?

How Clean is that…Fill, Site, Waste, Runoff?

In NSW the assessment of how "clean" is defined in relation to a site, to incoming fill or to soil to be disposed of, is regulated by different sections of the NSW Department of Environment and Climate Change (DECC). The different sections apply different guidelines and standards. The following discussion excludes the consideration of soil containing asbestos.

Site

Sites are assessed against acceptance criteria for a range of possible contaminants. The criteria depend on the intended use of the site

To assess a site soil samples are collected and analysed for a range of substances. The selection of the range of substances for which the soil is to be analysed should be based on the history of the site and therefore the possible contaminants. The number of sampling points required depends on the size of the site, with a minimum of 5 sampling points, each point characteristically sampled at several depths. In addition to the basic samples, there must be blind and split replicates, blanks and rinsate samples analysed. The 95% Upper Confidence Level (95% UCL) of the average for the basic samples must be compared with the acceptance criterion. That is, if the site passes, then there is a 95% probability or better that the average concentrations of the contaminants are below the acceptance criteria. Therefore as long as there are no significant hotspots it is possible for some results to be above the criteria.

Composited samples can be analysed for non volatiles thus reducing the cost, but the acceptance criterion is reduced by dividing it by the number of composited subsamples. Where contamination may be present compositing is not recommended, but it may save money when used as a screening tool where contamination is unlikely.

The acceptance criteria are divided into groups including:

  • Single house residential with poultry and home grown produce contributing more than 10% of the fruit and vegetable intake. This criterion is applied to most single houses with yards even though poultry or home grown produce is not a realistic option:
  • Residential, children’s day-care centres, preschools, primary schools with gardens and accessible soil where home grown produce contributes less than 10% and there is no poultry;
  • Residential with minimal access to soil, including high-rise apartments and flats.
  • Parks, secondary schools, recreational open space, playing fields;
  • Commercial, industrial and
  • Garden beds

The criteria also contain requirements for odour and ascetic factors. At times even soil containing nothing other than broken pieces of brick may be considered unsuitable.

A typical program of site assessment and possible cleanup includes the conduct of a site history investigation, sampling, and if contaminated, preparation of a Remedial Action Plan (RAP), followed by remediation (usually consisting of excavating the contaminated soil and taking it to a disposal facility), and validation sampling and analysis.

Disposal of Waste Soil

soil When soil is removed from a site and taken to a disposal facility, a Disposal Report is required as the facility is only licensed to accept certain classes of waste. The Report must classify the waste into classes such as Virgin Excavated Natural Material (VENM), Special Waste, Liquid Waste, Hazardous Waste, Restricted Solid Waste, General Solid (putrescibles) Waste, General Solid (non-putrescibles) Waste in accordance with the Waste Classification Guidelines – Part 1: Classifying Waste DECC 2008.

A series of Resource Recovery Exemptions exist in addition to the Waste Classification Guidelines. Should the waste material be classified under one of the exemptions (e.g. the Excavated Natural Material Exemption), an alternative to disposing the material at a landfill facility may exist, that has financial and environmental benefits. For example material classified as Excavated Natural Material may be applied to the land as engineering fill or in earthworks.

While some waste materials are ‘pre-classified’ such as building and demolition waste, others require a chemical assessment. The chemical assessment involves analysing samples of the material for potential contaminants, as well as leachability of those contaminants via the TCLP (Toxicity Characteristic Leaching Procedure) test. The TCLP involves dripping an acidic solution through a sample of the waste material for a period of time to determine the mobility of the potential contaminants. The leachate is analysed for contaminant concentration.

The criteria for what is an acceptable level of contaminants on a site and the criteria for disposal of waste including contaminated soil are different from and independent of one another.

Fill and Crushed Concrete Material

soil

Fill imported on to a site should be sampled and analysed against the site criteria. The guidelines require that the site which is the source of the fill be visited and assessed visually. Its site history should be examined and care should be taken to ensure that the fill arriving onto the site is the same as the material examined and sampled at the source site.

Before accepting fill GETEX advises that you check that the material being imported onto your site has the appropriate documentation. Ensure the documentation includes sampling and analysis results, that the sampling and analysis program is adequate for the volume of soil received and that the assessment included an inspection of the source site and its history . Ensure the analysis certificate is for the same material as is being delivered to you.

Be careful moving untested soil around a site. If it later turns out to be contaminated the contamination can easily have been smeared around, resulting in increased clean up / remediation costs as we as extra validation costs.

Disposal of Liquid Waste

Liquid waste is usually treated in a specially designed facility. Liquid waste is subject to licensing under the Waste Minimisation and Management Regulation.

Generally, other liquids are those which may be discharged to sewer in accordance with a discharge licence, or those that may be discharged directly into waters under the Protection of Environment Operations Act (POEO), or those which may be discharged into waters in accordance with a licence issued under that Act.

EROSION AND SEDIMENT CONTROL PLAN AND SOIL AND WATER MANAGEMENT PLAN REQUIREMENTS

On many construction sites an Erosion and Sediment Control Plan (ESCP) or Soil and Water Management Plan (SWMP) may exist with sampling and analysis requirements that can range from simple Total Dissolved Solids analysis required prior to the discharge of a sediment basin through to complex water quality assessments of existing waterways that may include a background assessment, assessment during construction and assessment post construction.

Should assistance be required Getex are able to review the Development Application, ESCP and SWMP requirements of the project and develop a sampling and analysis program to meet their needs.

Getex can manage the entire sampling and analysis program, mitigating any conflict of interest that may arise by the site manager conducting its own sampling. In this scenario one of Getex’s experienced consultants will attend the site and conduct the required sampling.

Alternatively Getex can develop a sampling kit specific for the needs of the client and the ESCP or SWMP and courier kit directly to the site. Sampling kits include all required equipment, sampling containers, additional PPE (that is required in addition to standard construction site PPE), paperwork and step by step instructions that enable the client to conduct the sampling with ease.

For sites that will be in operation over a long period of time Getex can over approximately five sampling events establish a site specific relationship between Total Suspended Solids and Turbidity.

Turbidity can be used on sites as a quick and affordable measure of water quality required prior to water discharge once a site specific relationship between Total Suspended Solids and Turbidity is established.

This is especially important where speed is critical. i.e. when a full sediment basin that has been flocced requires discharge prior to a new storm event.

Download the "Soil Contamination – How Clean is that…Fill, Site, Waste, Runoff?" Information Sheet

Contact GETEX for assistance with your needs for Site, Waste, or Fill Assessment, Disposal Reports and Related Issues

GETEX OPERATES 24 Hours/day, 7 days per week : (02) 9889 2488 www.getex.com.au

Additional Services

Consulting, management, monitoring and inspection services covering:

Hazardous Materials

  • Lead, Silica, Dusts, Petroleum Products, Solvents, Gases
  • Inspections/Registers
  • Air Monitoring
  • Management Plans

    Occupational Hygiene Services
  • Airborne Contaminant monitoring
  • Workplace Assessments
  • Risk/Hazard Analysis

    Air & Water
  • Quality Assessment & Monitoring
  • Indoor/Commercial
  • Environmental/Industrial

Note 1: Please note that government approved documents and guidelines are updated from time to time. Please call Getex to ensure that you are working with the correct guidelines.

Note 2: The information in this document is provided for general information purposes only and must not be relied upon for application in practical situations. Specific and detailed advice must be obtained from GETEX before any information in this document is applied in a real life situation.

1. Ensure that the material to be received on site has been thoroughly visually assessed and that the analysis certificate makes specific reference as to whether the material is free of any type of ASBESTOS contamination.

+ Waste Disposal/Classification – Waste Disposal / Waste Classification Report

Waste Disposal / Waste Classification Report

What is a Disposal Report?

A Disposal Report (also sometimes referred to as a Waste Classification Report or Certificate) is required when applying to take non liquid waste to a Disposal Facility, and is commonly required when disposing of waste soil. [Environmental Guidelines: Assessment, Classification & Management of Liquid & Non-Liquid Wastes, 2004 and Protection of the Environment Operations Act 1997 (POEO Act)]. Disposal Facilities are licensed to accept certain classes of waste only. Waste is classified into Inert, Solid, Industrial, Hazardous, Special and so on, depending on the analysis and on leaching properties. Typically, Disposal Facilities will not accept waste without a Disposal Report.

How is a Disposal Report Generated?

Samples, usually of soil, must be taken and analysed under a controlled protocol which includes:

  • An adequate number of samples
  • An adequate spatial distribution of the samples
  • An adequate number of blanks, split replicates, blind replicates, rinsate blanks
  • Application of controlled field work techniques
  • An adequate analysis program by an accredited laboratory
  • Appropriate data review of the laboratory analysis results
  • The generation of a Report detailing the investigation, the Report conforming to Guidelines
  • The Report is to conclude with an assessment of the relevant class of Waste

Time Factors

Soil Disposal Reports are very often required urgently. This requirement commonly arises when a site is being cleaned up. The soil is excavated and stockpiled. The sampling, analysis and Report process takes time, and the site and perhaps equipment lie idle awaiting the Disposal Report.

Hence a rapid turnaround service for the sampling, analysis and report, even though it costs more, can save money on the project overall. GETEX provides expedited service at reasonable rates.

Experienced Staff

GETEX staff have the experience, qualifications and expertise to provide you with the service you need to obtain a Disposal Report in a short time frame. Customer Service Orientation

GETEX operates 24/7. Your call will be handled by experienced people with authority who can help you. We do not use message services.

GETEX Carries full Professional Indemnity Insurance with cover for asbestos work (GETEX also has a NATA accredited laboratory for asbestos fi bre counting and air volume measurement).

Asbestos Problems?

GETEX professionals are very experienced in asbestos work, so if your Disposal problem involves asbestos, contact GETEX.

Download the Waste Disposal / Classification Information Sheet (PDF)